Transition-State Dynamics in Complex Quantum Systems
نویسندگان
چکیده
A model is proposed for studying the reaction dynamics in complex quantum systems which complete mixing of states hindered by an internal barrier. Such are often treated transition-state theory, also known chemistry as RRKM but validity theory questionable when there no identifiable coordinate associated with The consists two Gaussian Orthogonal Ensembles (GOE) levels coupled to each other and wave functions entrance decay channels. We find that formula can be derived from under some easily justifiable approximations. In particular, assumption rates insensitive widths on far side barrier fulfilled broad range Hamiltonian parameters. More doubtful common transmission factor $T$ across unity or modeled a one-dimensional giving close above This not case model; we only approaches one special conditions likely without strong collective component Hamiltonian.
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ژورنال
عنوان ژورنال: Journal of the Physical Society of Japan
سال: 2021
ISSN: ['0031-9015', '1347-4073']
DOI: https://doi.org/10.7566/jpsj.90.114005